Effect of the Class C Fly Ash on Low-Reactive Gold Mine Tailing Geopolymers

Yibran Perera-Mercado, Ahmadreza Hedayat, Lori Tunstall, Cara Clements, Julia Hylton, Linda Figueroa, Nan Zhang, Héctor Gelber Bolaños Sosa, Néstor Tupa, Isaac Yanqui Morales, Reynaldo Sabino Canahua Loza

Research output: Contribution to journalArticlepeer-review

Abstract

Beneficiation of industrial wastes, such as mine tailings (MTs), through development of alternative eco-friendly geopolymer binders for construction composites offers a twofold environmental benefit, as it reduces the demand for cement and it increases the sustainability of industrial processes by creating a value-added product from an industrial byproduct. While MTs have the requisite composition for use as a geopolymer precursor, they are often low-reactive. This study explored the effect of Class C Fly Ash (FAc) on the geopolymerization of low-reactive gold MTs. A 10 M sodium hydroxide (NaOH) solution was used as the alkaline activator with four different concentrations of FAc (5, 10, 15 and 20 wt.%). The results indicated that the combination of FAc with the low-reactive gold MTs improved the physicochemical stability of the final geopolymerized samples, with a 95–120% increase in compressive strength, compared to the geopolymer samples of only low-reactive gold MTs. Although some of the strength improvement could be attributed to geopolymerization of the FAc itself, the presence of the FAc also improved the reactivity of the MTs, increasing the geopolymer production of the MTs. This study documents the positive effects of the FAc on gold MTs with low-calcium content and their conversion into sustainable inorganic composite geopolymers for the construction field.

Original languageEnglish
Article number2809
JournalPolymers
Volume14
Issue number14
DOIs
StatePublished - Jul 2022

Bibliographical note

Funding Information:
The research team gratefully acknowledges the financial support provided by the Universidad Nacional de San Agustín (UNSA) de Arequipa through its Joint Center for Mining Sustainability with the Colorado School of Mines.

Publisher Copyright:
© 2022 by the authors.

Keywords

  • class C fly ash
  • geopolymers
  • mine tailings
  • Rietveld method

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