Thermoluminescence and electron paramagnetic resonance (EPR) studies of mineral chrysocolla (dioptase)

P. Selvin, S. Watanabe, Jorge Sabino Ayala Arenas

Research output: Contribution to journalArticlepeer-review

Abstract

The natural mineral chrysocolla (CuSiO3·2H2O) has been investigated in terms of thermally stimulated luminescence and EPR measurements. The glow curves for natural samples present three glow peaks at 190, 357 and 450°C. Pre annealed and subsequently irradiated samples give rise to four glow peaks at 140°C, 193°C, 305°C and 450°C. The formation of Ho centers at the expense of water molecules present in the channels has been identified by EPR measurements.

Original languageEnglish
Pages (from-to)531-533
Number of pages3
JournalRadiation Physics and Chemistry
Volume61
Issue number3-6
DOIs
StatePublished - 2001
Externally publishedYes

Bibliographical note

Funding Information:
This work was supported by FAPESP and CNPq. One of us, P.C. Selvin gratefully acknowledges FAPESP for a fellowship. The help rendered by Mr. W.E.F. Ayta throughout the course of this study is gratefully acknowledged.

Keywords

  • Chrysocolla
  • EPR
  • SiO hole centers
  • Thermoluminescence

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